Abstract: Postdetonation energetic residues can have environmental impacts that present a risk to military training-range sustainment. As munitions with new explosive formulations are developed and fielded, quantitative methods for assessing their residues are needed. Command detonation (i.e., static firing) allows residue testing to occur early in the acquisition process; however, its representation of live-fire residue production is uncertain due to differences in the initiation mechanism and cartridge orientation. This study aims to validate residue testing by command detonation through statistical comparison of residue deposition rates between live fire and command detonation. Live-fire residues were collected from fourteen 81 mm IMX-104 mortar cartridges fired onto snow, and deposition rates were compared with previous command-detonation tests of the same munition. Average live-fire deposition rates were 8000 mg NTO (3-nitro-1,2,4-triazol-5-one), 60 mg DNAN (2,4-dinitroanisole), 20 mg RDX (1,3,5-trinitroperhydro-1,3,5-triazine), and 2 mg HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocane) per cartridge. Compared to command detonation, live fire of the study munition produced significantly greater residues of NTO (p < 0.0001) and RDX (p = 0.01) but not DNAN (p = 0.067). Although absolute deposition rates of some IMX-104 compounds differed, command detonation was successful at predicting the order of magnitude of each IMX-104 compound for the studied 81 mm munition.